Study on etching of diamond monocrystal by MnO2
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摘要: 在不同温度下,将金刚石在空气中单独刻蚀或与MnO2混在一起刻蚀,用表面形貌、刻蚀面积和单颗粒抗压强度来表征单晶表面刻蚀程度。结果表明:MnO2和空气都能刻蚀人造金刚石单晶表面,且随刻蚀温度升高刻蚀加剧。在相同刻蚀温度下,用MnO2刻蚀时,单晶的{111}面比{100}面刻蚀严重;而在空气中,其{100}面比{111}面刻蚀严重。金刚石单晶刻蚀后其{100}面易形成四边形坑,{111}面易形成金字塔形刻蚀坑。且MnO2刻蚀剂能够对金刚石表面刻蚀起促进作用,使刻蚀面积增大和最大刻蚀速率对应的温度降低,导致金刚石单颗粒抗压强度大幅下降。Abstract: In order to compare the surface etching of diamond monocrystal, diamond is etched directly in air or with MnO2 at different temperatures. The etching degree on the surface of diamond monocrystal was characterized by surface morphology, etching area and compressive strength of diamond single particle. The results show that both MnO2 and air can successfully etch the surface of synthetic diamond monocrystal. With the increasing of etching temperature, the etching of diamond single crystal by air and MnO2 intensifies. At the same temperature, when using MnO2 as an enchant, the {111} face is more heavily etched than the {100} one; while in air, the {100} face is more heavily etched than the {111} one. After etching, the morphology of the etched diamond {100} face tends to form quadrilateral pits, while the {111} face is easy to form inverted pyramid corrosion pits. In addition, MnO2 can promote the etching of diamond surface by expanding the etching area and decreasing the temperature of the maximum etching rate, so the compressive strength of diamond monocrystal decreases greatly.
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Key words:
- diamond monocrystal /
- surface etching /
- MnO2
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