Preparing and characterizing ultrafine diamond coated with titanium dioxide
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摘要: 以聚乙烯吡咯烷酮(PVP)为偶联剂,钛酸四丁酯(TBOT)为TiO2前驱体,氨水为催化剂,通过Stöber法制备核-壳结构的二氧化钛包覆微细金刚石(UFD@TiO2),研究溶液pH值、氨水及去离子水的加入量对UFD@TiO2的影响。采用XRD、SEM及DSC-TG等手段对UFD@TiO2进行表征,利用三点弯曲法测定添加UFD或UFD@TiO2的陶瓷结合剂试样的抗折强度,通过SEM观察陶瓷结合剂试样断口的微观形貌。实验结果表明:当溶液pH值约为8,氨水体积分数为0.8%,去离子水体积分数为0.8%时,TBOT水解生成的TiO2易在金刚石表面异质形核,可获得致密均匀的TiO2膜层;UFD@TiO2的起始氧化温度为650℃,比UFD的起始氧化温度583℃提高了67℃;UFD@TiO2-陶瓷结合剂试样的抗折强度比UFD-陶瓷结合剂试样的抗折强度提高了20.9%。
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关键词:
- Stöber法 /
- 二氧化钛包覆微细金刚石 /
- 核-壳结构 /
- 抗折强度 /
- 抗氧化性
Abstract: Using polyvinylpyrrolidone (PVP) as a coupling agent, tetrabutyl orthotitanate (TBOT) as the precursor of titanium dioxide, and ammonia as catalyst, the ultrafine diamond coated with titanium dioxide (UFD@TiO2) with core-shell structure was prepared by Stöber method. The influences of the pH value of the solution and the additions of ammonia and deionized water on the formation of UFD@TiO2 were studied. The phase composition, microphotograph and oxidation resistance of UFD@TiO2 were characterized by XRD, SEM and DSC-TG. The flexural strength of specimens of UFD-vitrified bond and UFD@TiO2-vitrified bond was tested by three point bending method. The fracture micro-morphologies of vitrified bond specimens were observed by SEM. Results showed that when the pH value was approximately 8 and the volume fractions of ammonia and deionized water were both 0.8%, TiO2 was heterogeneously nucleated on the surface of diamond with TBOT hydrolysis, evenly forming a dense layer of TiO2 film. The initial oxidation temperature of UFD@TiO2 was 650℃, which was 67℃ higher than that of the UFD. The flexural strength of UFD@TiO2-vitrified bond specimen was 20.9% higher than that of UFD-vitrified bond specimens.
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