Microstructure and mechanical property of CVD MT-Ti(C, N) coating with different C/N ratios
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摘要: 采用化学气相沉积法在硬质合金基体上沉积具有不同碳氮比的MT-Ti(C,N)涂层,通过扫描电子显微镜(SEM)、透射电子显微镜(TEM)、能谱仪(EDS)和纳米硬度仪、划痕仪分别对其微观组织和机械性能进行分析。研究结果表明:碳源对MT-Ti(C,N)涂层中的碳氮比起着至关重要的作用;其中,在现有单一的乙腈(CH3CN)中温化学涂层反应体系中,引入C2H4可以有效提高MT-Ti(C,N)涂层的碳氮比,且随着碳氮比的增大,MT-Ti(C,N)涂层的晶粒得到明显细化。与此相对应的纳米硬度、弹性模量和结合力也随C/N比发生显著变化。Abstract: Thin films of MT-Ti(C, N) with different nitrogen and carbon contents were prepared on cemented carbide substrates using the chemical vapour deposition. It was found that carbon source had decisive effect on the ratios of C/N, and that the microstructure of MT-Ti(C, N) varied as the ratios of C/N changed, which was analyzed by SEM, TEM and EDS. The results showed that C2H4 gas could help to increase the ratio of C/N compared to mono CH3CN, and that as the ratios of C/N increased, the grain size of MT-Ti(C, N) decreased. It was also shown that the ratios of C/N played an important role in the corresponding scratch resistance and nanohardness.
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Key words:
- mid-temperature /
- columnar grain /
- adhesion force /
- nanohardness
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