Effect of carbon dioxide on growth of diamond films
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摘要: 利用微波等离子体化学气相沉积法,以H2/CH4/CO2为混合气源,在Si基底上沉积金刚石膜,分析了微波功率和CO2对金刚石膜生长的影响。利用Raman光谱、扫描电子显微镜(SEM)和X射线衍射(XRD)表征金刚石膜,以得到样品质量、表面形貌、晶粒取向等信息。结果表明:适当提高微波功率,可以促进金刚石晶粒长大并提高(100)取向度;加入适量CO2,能提高金刚石膜质量和生长速率,并保持表面形貌不会发生明显变化,但随着CO2含量的增加,金刚石表面形貌发生较大变化,薄膜质量和沉积速率先提高后降低。Abstract: Diamond films are deposited on Si substrate with H2/CH4/CO2 as source using microwave plasma chemical vapor deposition method.The effect of microwave power and CO2 on the growth of diamond films is analyzed.The quality,surface morphology and grain orientation of diamond film are systematically characterized by Raman spectroscopy,scanning electron microscopy(SEM)and X-ray diffraction(XRD).The results show that an appropriate increase of microwave power could promote the diamond grain growth and increase the(100)orientation.It's also shown that adding an appropriate amount of CO2 could improve the quality and growth rate of diamond films,and maintain surface morphology.However,with the increase of CO2 content,the diamond surface morphology changes greatly and the quality and growth rate of diamond films increases firstly and then decreases.
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Key words:
- microwave plasma /
- chemical vapor deposition /
- diamond films
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