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金刚石热损伤抑制技术研究现状

张建华 李昂 胡婷婷 杜全斌 崔冰 张黎燕 王蕾 毛望军

张建华, 李昂, 胡婷婷, 杜全斌, 崔冰, 张黎燕, 王蕾, 毛望军. 金刚石热损伤抑制技术研究现状[J]. 金刚石与磨料磨具工程, 2024, 44(5): 563-574. doi: 10.13394/j.cnki.jgszz.2023.0166
引用本文: 张建华, 李昂, 胡婷婷, 杜全斌, 崔冰, 张黎燕, 王蕾, 毛望军. 金刚石热损伤抑制技术研究现状[J]. 金刚石与磨料磨具工程, 2024, 44(5): 563-574. doi: 10.13394/j.cnki.jgszz.2023.0166
ZHANG Jianhua, LI Ang, HU Tingting, DU Quanbin, CUI Bing, ZHANG Liyan, WANG Lei, MAO Wangjun. Research status of thermal damage inhibition technology for diamond[J]. Diamond & Abrasives Engineering, 2024, 44(5): 563-574. doi: 10.13394/j.cnki.jgszz.2023.0166
Citation: ZHANG Jianhua, LI Ang, HU Tingting, DU Quanbin, CUI Bing, ZHANG Liyan, WANG Lei, MAO Wangjun. Research status of thermal damage inhibition technology for diamond[J]. Diamond & Abrasives Engineering, 2024, 44(5): 563-574. doi: 10.13394/j.cnki.jgszz.2023.0166

金刚石热损伤抑制技术研究现状

doi: 10.13394/j.cnki.jgszz.2023.0166
基金项目: 河南省科技攻关计划(222102230111; 222102220114; 202102210072; 232102220058)。
详细信息
    通讯作者:

    杜全斌,男,1983年生,博士、副教授。主要研究方向:先进焊接材料与装备、超硬工具制备技术与装备、金刚石热界面材料开发、激光增材表面修复再制造。E-mail:paperduqb@126.com

  • 中图分类号: TH16; TQ164; TG42; TG74; TG14

Research status of thermal damage inhibition technology for diamond

  • 摘要: 金刚石工具制备过程中的金刚石热损伤主要包括金刚石的石墨化、金刚石的破损开裂和金刚石的化学侵蚀等。针对金刚石热损伤问题,分别从金刚石表面镀覆、胎体材料性能调控和成型技术优化3个方面,介绍了目前金刚石热损伤的抑制技术,并对未来研究方向进行了展望,以期为高性能金刚石工具制备提供参考和指导。

     

  • 图  1  Ni沿金刚石晶界诱导的石墨化过程[6]

    Figure  1.  Graphitization process induced by Ni along diamond grain boundaries[6]

    图  2  非受控冷却下钎焊连接处的应力计算分析[13]

    Figure  2.  Calculation analysis of stress developed with brazed joints during uncontrolled cooling[13]

    图  3  界面处与金刚石的裂纹扩展[13]

    Figure  3.  Crack expansion on interface and diamond[13]

    图  4  金刚石表面的反应产物Cr3C2形貌[14]

    Figure  4.  Morphology of reaction product Cr3C2 on diamond surface[14]

    图  5  金刚石表面的生成物形貌[32]

    Figure  5.  Morphology of reaction product on diamond surface[32]

    图  6  Hf元素对金刚石热损伤机制的影响[47]

    Figure  6.  Effect of the Hf element on thermal damage mechanism of diamond[47]

    图  7  不同GNPs添加量时的复合钎料钎焊金刚石表面碳化物形貌[55]

    Figure  7.  Morphologies of carbide on diamond surface brazed by composite filler metal with different GNPs contents[55]

    图  8  不同GNPs添加量时的复合钎料钎焊金刚石表面石墨化程度[56]

    Figure  8.  Graphitization degree of diamond surface brazed by composite brazing filler metal with different GNPs contents[56]

    图  9  激光钎焊过程金刚石界面元素扩散反应示意图[68]

    Figure  9.  Schematic diagram of element diffusion reaction on diamond interface during laser brazing process[68]

    图  10  真空钎焊过程金刚石界面元素扩散反应示意图[68]

    Figure  10.  Schematic diagram of element diffusion reaction on diamond interface during vacuum brazing process[68]

    表  1  各类金刚石镀层方法的特点[17]

    Table  1.   Characteristics of various diamond coating methods[17]

    技术特征 镀层成分 结合状态 镀覆温度t / ℃ 金刚石热损伤
    CVD Ti、Mo、W、Cr
    及对应碳化物
    冶金结合 >850
    PVD Ti、Mo、W、
    Cr、Ni、B
    物理结合 < 400
    电镀 Ni、Ni-W合金、
    W-Co合金
    机械包覆 < 100
    熔盐法 Ti、Mo、W、Cr
    及对应碳化物
    冶金结合 850~1 100
    预钎焊 Ni基合金、Cu基
    合金、Ag基合金
    冶金结合 > 850
    真空微蒸镀 Ti、Mo、W、Cr
    及对应碳化物
    冶金结合 650~750
    下载: 导出CSV
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出版历程
  • 收稿日期:  2023-08-21
  • 修回日期:  2023-11-22
  • 录用日期:  2023-12-06
  • 网络出版日期:  2023-12-11
  • 刊出日期:  2024-10-01

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