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(Ti,Nb)Cx 复合材料的制备与性能表征

邹芹 任宇 李艳国 任海波

邹芹, 任宇, 李艳国, 任海波. (Ti,Nb)Cx 复合材料的制备与性能表征[J]. 金刚石与磨料磨具工程, 2024, 44(5): 575-580. doi: 10.13394/j.cnki.jgszz.2023.0164
引用本文: 邹芹, 任宇, 李艳国, 任海波. (Ti,Nb)Cx 复合材料的制备与性能表征[J]. 金刚石与磨料磨具工程, 2024, 44(5): 575-580. doi: 10.13394/j.cnki.jgszz.2023.0164
ZOU Qin, REN Yu, LI Yanguo, REN Haibo. Preparation and performance characterization of (Ti,Nb) Cx composite material[J]. Diamond & Abrasives Engineering, 2024, 44(5): 575-580. doi: 10.13394/j.cnki.jgszz.2023.0164
Citation: ZOU Qin, REN Yu, LI Yanguo, REN Haibo. Preparation and performance characterization of (Ti,Nb) Cx composite material[J]. Diamond & Abrasives Engineering, 2024, 44(5): 575-580. doi: 10.13394/j.cnki.jgszz.2023.0164

(Ti,Nb)Cx 复合材料的制备与性能表征

doi: 10.13394/j.cnki.jgszz.2023.0164
基金项目: 河北省高校科研重点项目(ZD2021099)。
详细信息
    作者简介:

    邹芹,女,1978,教授。主要研究方向:超硬及特种陶瓷材料。E-mail:zq@ysu.edu.cn

    李艳国,男,1978,副研究员。主要研究方向:先进钢铁材料。E-mail:lyg@ysu.edu.cn

  • 中图分类号: TG71; TB332

Preparation and performance characterization of (Ti,Nb) Cx composite material

  • 摘要: 以TiC与过渡族金属Nb为原料,在机械合金化(mechanical alloying , MA)下制备多种非化学计量比的(Ti, Nb) Cx 聚晶金刚石(polycrystalline diamond, PCD)刀具结合剂。通过X射线衍射仪对复合材料烧结体的物相组成等进行分析,再通过扫描电子显微镜对复合材料的断口形貌进行观察,并用维氏硬度计测量复合材料的硬度和断裂韧性。结果表明:在13001700 ℃的范围内,温度越高TiC和 Nb的固溶程度越好;在同一烧结温度下,(Ti, Nb) Cx复合材料的硬度随着金属Nb占比变大而逐渐升高;在同一金属Nb占比下,温度越高Nb与TiC的固溶程度越好。同时, (Ti, Nb) C0.5复合材料的力学性能最优,在1600 ℃时达到硬度最大值23.0 GPa,且其断裂韧性最高为7.20 MPa·m1/2

     

  • 图  1  不同烧结温度下(Ti, Nb) ${\rm{C}}_x$的XRD图谱

    Figure  1.  XRD patterns of (Ti,Nb) ${\rm{C}}_x$ at different sintering temperatures

    图  2  不同烧结温度下的(Ti, Nb) C0.8断口形貌

    Figure  2.  Fracture morphology of (Ti, Nb) C0.8 at different sintering temperatures

    图  3  不同烧结温度下的(Ti, Nb) C0.8粒径分布

    Figure  3.  Grain size distributions of (Ti, Nb) C0.8 at different sintering temperatures

    图  4  1600 ℃下(Ti, Nb)${\rm{C}}_x$烧结体的SEM形貌

    Figure  4.  SEM morphology of (Ti, Nb) ${\rm{C}}_x$ sintered body at 1600

    图  5  (Ti, Nb)C0.5 、(Ti, Nb)C0.8的晶胞参数图

    Figure  5.  Cell parameters of (Ti, Nb) C0.5 and (Ti, Nb) C0.8

    图  6  不同烧结温度下(Ti, Nb) ${\rm{C}}_x $的硬度与断裂韧性

    Figure  6.  Hardness and fracture toughness of (Ti, Nb) ${\rm{C}}_x $ at different sintering temperatures

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出版历程
  • 收稿日期:  2023-08-18
  • 修回日期:  2023-11-15
  • 录用日期:  2023-12-06
  • 网络出版日期:  2023-12-11
  • 刊出日期:  2024-10-01

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