陶瓷结合剂金刚石团聚磨料探索

成晓哲; 许衍; 穆云超; 韩敬贺; 刘涛

doi:10.13394/j.cnki.jgszz.2023.0022

陶瓷结合剂金刚石团聚磨料探索

doi: 10.13394/j.cnki.jgszz.2023.0022

成晓哲^1,,
许衍¹,
穆云超^1, ,,
韩敬贺²,
刘涛³

1.
中原工学院, 郑州 451191
2.
河南省惠丰金刚石有限公司, 郑州 450008
3.
国家磨料磨具质量检验检测中心, 郑州 450001

基金项目: 国家自然科学基金（51602356）。

详细信息

作者简介:
成晓哲，男，1986年生，博士、讲师。主要研究方向：超硬材料及相关功能性应用。E-mail：mschengzhe@163.com

通讯作者:
穆云超，男，1971年生，博士、教授。主要研究方向：超硬材料及制品。E-mail：yunchaomu@126.com

中图分类号: TQ164; TB321; TB34; TG58
计量
- 文章访问数: 473
- HTML全文浏览量: 277
- PDF下载量: 81
- 被引次数: 0
出版历程
- 收稿日期: 2023-02-05
- 修回日期: 2023-04-15
- 网络出版日期: 2023-11-06
- 刊出日期: 2024-02-20

Exploration of ceramic binder diamond aggregated abrasives

1.
Zhongyuan University of Technology, Zhengzhou 450007, China
2.
Henan Huifeng Diamond Co., Ltd., Zhengzhou 450008, China
3.
National Quality Supervision & Inspection Center For Abrasives, Zhengzhou 450008, China

摘要

摘要: 细粒度金刚石微粉大量积压是目前金刚石微粉制造行业面临的问题之一，为促进其应用，以铝硼硅结合剂为黏接剂、Si粉和Ti粉为添加剂制造团聚磨料试样，并将制成的团聚磨料加入铝硼硅结合剂中制成陶瓷结合剂试样，对所制试样的抗弯强度、物相构成和微观形貌进行分析。结果表明：添加Si或Ti的铝硼硅黏结剂均能起到团聚金刚石的作用；当团聚磨料中Si或Ti的质量分数为10.0%时，所制得的陶瓷结合剂试样抗弯强度最大，且添加Si的团聚磨料试样抗弯强度为43.74 MPa；当Si或Ti的质量分数超过10.0%时，团聚磨料试样中出现大量Si或者TiO₂峰，其抗弯强度急剧下降；添加Si的团聚磨料试样与添加Ti的团聚磨料试样相比，其具有更大的粒度和更均匀的粒度分布，添加Si的铝硼硅黏结剂可将1～2 μm的磨料团聚为5～10 μm的磨料。
- 团聚磨料 /
- 金刚石微粉 /
- 陶瓷结合剂 /
- 磨料性能
Abstract: The diamond powder manufacturing industry at present grapples with a large backlog of fine-grained diamond powders. To enhance its applicability, agglomerated abrasive samples were manufactured with aluminum-borosilicate binder as the bonding agent, Si powder and Ti powder as additives. These agglomerated abrasive samples were then added into an aluminum-borosilicate binder to create ceramic bond samples. The bending strength, phase composition, and microscopic morphology of the samples were analyzed. The results show that the Al-B-Si binder, when combined with Si or Ti, can agglomerate diamond. When the mass fraction of Si or Ti in the agglomerated abrasives is 10.0%, the bending strength of the ceramic bond samples prepared is the largest. The bending strength of the agglomerated abrasive sample with Si added is 43.74 MPa. When the mass fraction of Si or Ti exceeds 10.0%, a large number of Si or TiO₂ peaks appear in the agglomerated abrasive samples, and its bending strength decreases sharply. Compared with the agglomerated abrasive sample added with Ti, the agglomerated abrasive sample added with Si has a larger particle size and a more uniform particle size distribution. 1～2 μm abrasives can be aggregated into 5～10 μm abrasives with the addition of Al-B-Si binder with Si.
- agglomerated abrasive /
- fine-grained diamond powder /
- ceramic binder /
- abrasive performance

HTML全文

图 1 1号团聚磨料试样外观形貌

Figure 1. Appearance of No. 1 agglomerated abrasive samples

下载: 全尺寸图片幻灯片

图 2 1号陶瓷结合剂试样外观形貌

Figure 2. Appearance of No. 1 ceramic bonder samples

下载: 全尺寸图片幻灯片

图 3 650、700和750 ℃下制备的陶瓷结合剂试样的抗弯强度

Figure 3. Bending strengths of ceramic bond specimens prepared at 650，700 and 750 ℃

下载: 全尺寸图片幻灯片

图 4 700 ℃下制备的2号陶瓷结合剂试样的微观形貌

Figure 4. Micromorphology of No. 2 ceramic bond sample prepared at 700 ℃

下载: 全尺寸图片幻灯片

图 5 700 ℃烧结时不同Si质量分数的团聚磨料XRD图谱

Figure 5. XRD patterns of agglomerated abrasives with different Si mass fractions sintered at 700 ℃

下载: 全尺寸图片幻灯片

图 6 700 ℃烧结时不同Ti质量分数的团聚磨料XRD图谱

Figure 6. XRD patterns of agglomerated abrasives with different Ti mass fractions sintered at 700 ℃

下载: 全尺寸图片幻灯片

图 7 700 ℃烧结时2号团聚磨料的微观形貌

Figure 7. Micromorphology of No. 2 agglomerated abrasive sintered at 700 ℃

下载: 全尺寸图片幻灯片

图 8 700℃烧结时6号团聚磨料微观形貌

Figure 8. Micromorphology of No. 6 agglomerated abrasive sintered at 700 ℃

下载: 全尺寸图片幻灯片

表 1 实验设备

Table 1. Experimental equipments

实验仪器及设备	型号	生产厂家
放电等离子烧结炉	SPS-40-10	上海皓越
马弗炉	SX 2-4-10	上海意丰
X射线衍射仪	UITIMA IV	日本理学Rigaku
扫描电子显微镜	Inspect S50	FEI
万能材料试验机	Ae-20I	日本岛津公司
行星式球磨机	XM-4×05	湘潭华丰仪器

下载: 导出CSV

表 2 团聚磨料试样配方

Table 2. Formula of agglomerated abrasive samples

试样编号	Al₂O₃ 质量分数 ω₁ / %	SiO₂ 质量分数 ω₂ / %	B₂O₃ 质量分数 ω₃ / %	无水Na₂CO₃ 质量分数 ω₄ / %	无水K₂CO₃ 质量分数 ω₅ / %	Si 质量分数 ω₆ / %	Ti 质量分数 ω₇ / %	金刚石体积分数 φ₁ / %
1	17.4	26.1	43.5	4.0	4.0	5.0		60
2	16.4	24.6	41.0	4.0	4.0	10.0		60
3	15.4	23.1	38.5	4.0	4.0	15.0		60
4	14.4	21.6	36.0	4.0	4.0	20.0		60
5	17.4	26.1	43.5	4.0	4.0		5.0	60
6	16.4	24.6	41.0	4.0	4.0		10.0	60
7	15.4	23.1	38.5	4.0	4.0		15.0	60
8	14.4	21.6	36.0	4.0	4.0		20.0	60

下载: 导出CSV

表 3 陶瓷结合剂试样配方

Table 3. Ceramic bonder sample formula

组成	取值
Al₂O₃ ω₁ / %	18.4
SiO₂ ω₂ / %	27.6
B₂O₃ ω₃ / %	46.0
无水Na₂CO₃ ω₄ / %	4.0
无水K₂CO₃ ω₅ / %	4.0
团聚磨料体积分数 φ₂ / %	40

下载: 导出CSV

参考文献(26)

[1]	CHOUDHARY D, BELLARE J. Manufacture of gem quality diamonds: A review [J]. Ceramics International,2000,26(1):73-85. doi: 10.1016/S0272-8842(99)00022-X
[2]	ZHANG Y, RHEE K Y, HUI D, et al. A critical review of nanodiamond based nanocomposites: Synthesis, properties and applications [J]. Composites Part B: Engineering,2018,143:19-27. doi: 10.1016/j.compositesb.2018.01.028
[3]	张书达, 张文刚, 王松. 金刚石微粉和抛光液的制造工艺检测技术及应用(上) [J]. 超硬材料工程,2012,24(1):24-28. ZHANG Shuda, ZHANG Wengang, WANG Song. Manufacturing process and testing technology for diamond micron powder and diamond polishing suspension [J]. Superhard Material Engineering,2012,24(1):24-28.
[4]	吴元康. 纳米晶多晶体金刚石超细微粉在表面技术中的应用 [J]. 表面技术,2007,36(6):64-65. WU Yuankang. Nano-polycrystal diamond superfine powders and its application in surface techniques [J]. Surface Technology,2007,36(6):64-65.
[5]	王艳辉, 李晓虎, 常锐, 等. 金刚石微粉表面镀覆对线锯的关键作用分析 [J]. 金刚石与磨料磨具工程,2013(3):26-30. WANG Yanhui, LI Xiaohu, CHANG Rui, et al. Effect of coated diamond micro powder on diamond wire saw manufacturing technology [J]. Diamond & Abrasives Engineering,2013(3):26-30.
[6]	SHAMES A I, MOGILYANSKY D, PANICH A M, et al. XRD, NMR, and EPR study of polycrystalline micro- and nano-diamonds prepared by a shock wave compression method [J]. Physica Status Solidi A,2015,212(11):2400-2409. doi: 10.1002/pssa.201532154
[7]	SHIMAOKA T, KOIZUMI S, TANAKA M M. Diamond photovoltaic radiation sensor using pn junction [J]. Applied Physics Letters,2018,113(9):093504.1-093504.4.
[8]	YANG S, WAN X, WEI K, et al. A new sustainable concept for silicon recovery from diamond wire saw silicon powder waste: Source control and comprehensive conservation [J]. Journal of Cleaner Production,2022,358:131961.1-131961.13.
[9]	周波, 毛剑波. 金刚石线锯质量检验 [J]. 金刚石与磨料磨具工程,2017,37(2):73-77. ZHOU Bo, MAO Jianbo. Quality inspection method for diamond wire saw [J]. Diamond & Abrasives Engineering,2017,37(2):73-77.
[10]	WU X, TAN Y, WU H, et al. Structural modification of diamond-wire-cut multicrystalline Si by Cu-catalyzed chemical etching for surface structuring [J]. Thin Solid Films,2022,750:139199-139205. doi: 10.1016/j.tsf.2022.139199
[11]	PANIGRAHI N, CHAINI R, NAYAK A, et al. Impact of milling time and method on particle size and surface morphology during nano particle synthesis from α-Al₂O₃ [J]. 2018, 5(9): 20727-20735.
[12]	SHIN H, LEE S, JUNG H S, et al. Effect of ball size and powder loading on the milling efficiency of a laboratory-scale wet ball mill [J]. Ceramics International,2013,39(8):8963-8968. doi: 10.1016/j.ceramint.2013.04.093
[13]	NUNES D, LIVRAMENTO V, MARDOLCRA U V, et al. Tungsten nanodiamond composite powders produced by ball milling [J]. Journal of Nuclear Materials,2012,426(1/2/3):115-119. doi: 10.1016/j.jnucmat.2012.03.028
[14]	FADDA S, CINCOTTI A, CONCAS A, et al. Modelling breakage and reagglomeration during fine dry grinding in ball milling devices [J]. Chemical Engineering Transactions,2009,17:687-692.
[15]	CHEN J, SUN T, SU J, et al. A novel agglomerated diamond abrasive with excellent micro-cutting and self-sharpening capabilities in fixed abrasive lapping processes [J]. Wear,2021,464/465:203531-203539. doi: 10.1016/j.wear.2020.203531
[16]	WANG Z, NIU F, WANG Z, et al. Friction and wear characteristics of agglomerated diamond abrasives and lapping performance of fixed agglomerated diamond pads [J]. Wear,2021,470/471(1):203598-203611.
[17]	NIU F, WANG K, SUN T, et al. Lapping performance of mixed-size agglomerated diamond abrasives in fixed abrasives pads [J]. Diamond and Related Materials,2021,118:108499-108458. doi: 10.1016/j.diamond.2021.108499
[18]	朱永伟, 沈琦, 王子琨, 等. 多晶金刚石固结磨料研磨垫精研石英玻璃的性能探索 [J]. 红外与激光工程,2016,45(10):6-10. ZHU Yongwei, SHEN Qi, WANG Zikun, et al. Lapping performance on quartz glass of fixed abrasive pad embedded with multi-grain diamond grits [J]. Infrared and Laser Engineering,2016,45(10):6-10.
[19]	陈春晖, 陈哲, 刘一波, 等. 类多晶(堆积)磨料的研究现状与应用 [J]. 超硬材料工程,2020,32(2):6-11. CHEN Chunhui, CHEN Zhe, LIU Yibo, et al. Research status and application of agglomerate abrasives [J]. Superhard Material Engineering,2020,32(2):6-11.
[20]	栗正新, 王兆武. 堆积磨料的研究开发与应用 [J]. 中原工学院学报,2016,27(3):4-8. doi: 10.3969/j.issn.1671-6906.2016.03.012 LI Zhengxin, WANG Zhaowu. Research and application of stacked abrasives [J]. Journal of Zhongyuan University of Technology,2016,27(3):4-8. doi: 10.3969/j.issn.1671-6906.2016.03.012
[21]	SHAO W Z, IVANOV V V, ZHEN L, et al. A study on graphitization of diamond in copper–diamond composite materials [J]. Materials Letters,2004,58(1/2):146-149.
[22]	FEDOSEEV D V, VNUKOV S P, BUKHOVETS V L, et al. Surface graphitization of diamond at high temperatures [J]. Surface and Coatings Technology,1986,28(2):207-214. doi: 10.1016/0257-8972(86)90059-9
[23]	CHENG X, WANG Y, LIANG Y, et al. Avoiding the oxidation of SiC in SiC-borosilicate glass composites by adding zinc [J]. Corrosion Science,2015,90:413-419. doi: 10.1016/j.corsci.2014.10.039
[24]	ZHANG X, WANG Y, ZANG J, et al. Improvement of thermal stability of diamond by adding Ti powder during sintering of diamond/borosilicate glass composites [J]. Journal of the European Ceramic Society,2011,31(10):1897-1903. doi: 10.1016/j.jeurceramsoc.2011.04.009
[25]	关振铎. 无机材料物理性能[M]. 北京: 清华大学出版社, 1992. GUAN Zhenduo. Physical properties of inorganic materials [M]. Beijing: Tsinghua University Press, 1992.
[26]	田英良, 孙诗兵. 新编玻璃工艺学 [M]. 北京: 中国轻工业出版社, 2009. TIAN Yingliang, SUN Shibing. New glass technology [M]. Beijing: China Light Industry Press, 2009.